No, lions are African and Asian and alligators are American. They do not live on the same continent.
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Lions are not typically found in the same habitats as alligators, but in some circumstances, lions may prey on alligators if they come in contact. However, such interactions are rare due to their different habitats and food preferences.
Mountain lions prey on alligators, but on a less frequent time. There is an incident where a mountain lion killed an american alligator by ambush.
Alligators will eat other alligators on occasion. A mother alligator will generally watch over her brood for a while, once they're in the water, but eventually her instincts tell her it's time to leave. After that...any small animal in the water is potentially food, even her young.
Crocodiles have been known to kill lions, and sometimes the lion gets away, or kills the crocodile. Alligators do not live in Africa.
How are they different
Adult alligators have few natural predators, but larger alligators or crocodiles, jaguars, and large birds of prey such as eagles may prey on younger alligators. In addition, humans may also consume alligators' eggs or meat.
lions eat ibex