In Ruby and Sapphire, a little girl with brown pigtails and a red-orange dress who has two Pokéblock cases gives you one in Slateport Contest Hall.
Whereas, in Emerald, the same girl gives it to you but in Lilycove Contest Hall.
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If you go to Slateport city there is a contest hall. Inside there is a girl talk to her. She will say "I've already got 2 so u can have the other one" and she will give a poke block case to you.
You can find it inside the Contest House in Lilycove City. Talk to the little girl inside, and she'll give you a PokeBlock Case
please help me were do you get IT!!! oh sorry any way look around slateport city
get it in the contest hall in slateport city talk to the girl inside the hall she will say i have 2. have 1. she will then give it to you.
You can get it by blending berries at every Pokemon contest (inside a blending machine).
you can find a poke block case in slateport city.go in the Pokemon contest place and talk to a little girl.she will say she has 2 of them and will give you 1.