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The COD can be estimated from the concentration of oxidizable compound in the sample, based on its stoichiometric reaction with oxygen to yield CO2 (assume all C goes to CO2), H2O (assume all H goes to H2O), and NH3 (assume all N goes to NH3), using the following formula:COD = (C/FW)(RMO)(32)Where C = Concentration of oxidizable compound in the sample,FW = Formula weight of the oxidizable compound in the sample,RMO = Ratio of the # of moles of oxygen to # of moles of oxidizable compound in their reaction to CO2, water, and ammonia

For example, if a sample has 500 wppm of phenol:C6H5OH + 7O2 → 6CO2 + 3H2OCOD = (500/94)(7)(32) = 1191 wppm

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Q: How do you calculate COD value in a sample?
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