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The first 100.00 bill was produced in 1862. A United Sates Note. there were also Compound Interest Treasury Notes, Interest Bearing Notes, National Gold Bank Notes, and Gold Certificates
Please check your bill again. As the banner across its top indicates, it's a United States Note and not a gold certificate or gold note. The US hasn't printed gold bills since the 1920s, and the last $5 gold notes was issued from 1870 to 1874. There's more information the at question "What is the value of a 1963 US 5 dollar bill with a red seal?"
The government stopped the issue of gold certificate in 1933 You probably have a US Note - it'll say UNITED STATES NOTE right at the top of the bill over Jefferson's picture. Please see the Related Question for more information.
1928 $50 bills were issued as gold certificates and as Federal Reserve Notes but they're not the same. Please check the wording across your bill's top front as well as its seal color*; then see one of the following questions: "What is the value of a 1928 US 50 dollar Federal Reserve Note?""What is the value of a 1928 US 50 dollar gold certificate?"* Gold certificates have gold seals and FRNs have green seals.
Please check the banner across the top of your bill. It should say United States Note, not gold certificate. There's never been a $2 Gold Certificate and in any case, all gold certificates of any denominations were withdrawn from circulation in 1933. There's more information the at question "What is the value of a 1963 US 2 dollar bill?".