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Because it's pronounced as yewnit. The use of 'a' and 'an' depends on prinunciation, not spelling. Compare words like 'a uniform', 'an hour', ...
because the U in unit sounds like "yoo." "An" is put if the beginning of the word sounds like a vowel. that's why it's "an hour" instead of "a hour." the H sounds like an O.

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Q: Why 'a unit' not 'an unit'?
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