Potomac River runs along the west side of Washington DC. The Anacostia River is in the southern part of DC.
Yes, Washington DC is located on the Potomac River on the Eastern side of the USA.
Virginia is west and south of Washington DC.
No. Washington state is in the Pacific northwest, on the west coast of the US, while Washington DC is located on the Potomac River between Maryland and Virginia (near the east coast of the US).
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My head
I assume you mean Washington DC. Washington is a state on the west coast. And no, Washington DC is it's own "State".