You are not able to block any phone number manually from any cell phone. You could call your cell phone carrier and ask them to block the phone number for you. You can also put the contact you wish to ignore in a ignore list where your phone will not ring or vibrate when they try to call or text you.
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Depends where you are?
O2 users in the UK just can't!
This guy has a campaign to get this added as a feature
http://www.guardianforce.co.uk/2009/gadgets-tech/iphone-the-campaign/
You'll need to go to the Apple site to get it added (Follow the links)
You don't have a reject list featured in an iphone .. However you can buy an application related to it & bingo your problem's solved :)
No. You cannot block calls from Apple iPhones. However, you can purchase and download apps that enable you to block calls.
Tap on Settings, scroll down to "Phone" (or "Messages" if you want to block texts, too) and tap on "Blocked" to enter the number you want to block.