Moscow, the capital. Otherwise St. Petersburg, Gorky, Nizny Novgorod, Vladivostok, Yekaterinburg.
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The country with the second largest capital city in the world is Russia, with Moscow being its capital.
Birmingham is the second largest city in Britain after London.
Mexico - North America's largest city, Mexico City, is located in Mexico. It is also the world's second-largest city.
Canada has the second largest area in the world, after Russia.
If you mean strictly in landmass, Canada. It is second only to Russia and encompasses 7% of the worlds land.