Yes, blessed ashes are a sacramental.
Some Christian congregations have rules about marriage. If the marriage is done according to the rules of the religion, it is sacramental. All other marriages are non-sacramental.
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Yes
there is seven sacraments
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The pastor is the official witness of a sacramental marriage, with his permission, an assistant priest, or a deacon may witness it instead.
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A sacrament is a religious ceremony or ritual. The bible is not a sacrament.