Unconscious means that the person is not awake (in a coma) but may have intact vital functions. (Is breathing, has a pulse).
Unresponsive means that the person does not respond to verbal or tactile stimuli. (without making any assessment of his vital status)
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Unconscious means that one is not responding to any normal brain activity. The unresponsive or unconsious state usually comes first in the case of an accident. After a certain amount of time without oxygen flowing to the brain, then one may slip into a coma. This means that there is a heart beat but one appears to be in a deep sleep with little or no brain activity.
Unresponsive can mean a person would rather not speak/respond to your comment or they are seriously ill and cannot respond. Non-responsive means not responding because they choose to or not reacting to a medical examination.
Unconsciousness refers to a lack of awareness and responsiveness to stimuli, while unresponsiveness can include both a lack of response and a lack of reaction to stimuli. Unconsciousness generally implies a more profound lack of awareness than just being unresponsive.