The word right here is an adjective, always is an adverb (modifies right) and not is an adverb (modifies always).
E.g. I am not always right.
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No adverb is better than any other; each adverb has its particular use, to convey a specific meaning. Choosing the right word depends upon what you are trying to say. There is no single right word which is always the right one to use in all cases.
I am not sure but NOT is an adverb of negation. Examples: No Not Never Don't
adverb of frequency, like - sometimes always often
No. Unlike fast and slow, speedy is always an adjective. The adverb is speedily.
Yes, along with other adverbs like seldom always never, it is an adverb of frequency.