It can be, when it is used to mean "freely" (e.g. the bottom half was dangling free, the fish swam free).
Otherwise, free is an adjective meaning independent, unattached, or at no cost.
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No, it is not an adverb. The word dollar is a noun. There is no adverb form.
The word he is a pronoun; an adverb modifies a verb or an adverb.
Yes. An adverb can modify a verb, an adjective or another adverb.
The word not is an adverb. The word there can be an adverb. The combination "not there" is a compound adverb.The homophone phrase "they're not" includes a pronoun, a verb, and an adverb, because the adverb not has to modify an understood adjective or adverb (e.g. "They're not colorful).
No, excellent is an adjective. The adverb form is excellently.