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The outer valence electron lies in a 1s orbital in Hydrogen. The effective nuclear charge of hydrogen can be taken as Z = 1. The electron that is being ionised in Oxygen lies in a 2p orbital which has an effective nuclear charge of Z = 8-(3.4 or 4.5 or something). The point is, this nuclear charge at a greater distance from the nucleus means the energies of the electrons are similar and so ionisation energis required are too similar.

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The first ionization energy of hydrogen and oxygen is the same because both elements have one electron in their outermost shell, which is easier to remove compared to other electrons located closer to the nucleus. This results in the same amount of energy required to remove the outermost electron in both elements.

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9mo ago
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Q: Why is the first ionisation energy of hydrogen and oxygen the same?
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