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A Salt-Bridge can be constructed using a glass tube filled with a high concentration of an inert salt such as KCl that employs a porous plug at both ends, a saline soaked piece of paper or cardboard, or a fritted-glass disk. In any case, the salt-bridge is arranged so that inert ions can flow between the half-cells, but gross mixing of the half-cell solutions is prevented. As the Battery operates, Cl-, in the case of the glass-tube construction, will flow from the Salt-Bridge into the Anode so as to counter the build-up of Positive Ions. At the same time, K+ ions will flow into the Cathode to replace the depleted Positive Ions. KCl is frequently used for Salt-Bridge construction because the ionic mobilities of K+ adn Cl- are nearly equal.

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2w ago

Salt bridges are used in cells because they allow ions to flow between the two half-cells to balance the charges and complete the circuit without allowing direct mixing of the electrolytes. This prevents unwanted chemical reactions between the two half-cells and maintains the integrity of the cell. Using wires would lead to undesirable side reactions and could cause the cell to lose efficiency.

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Q: Why is salt bridge used in the construction of the cell instead of the wires?
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