G ≡ H -TS (or in another useful form dG = dH -TdS)
where
H is enthalpy
T is absolute temperature
S is entropy
The name of the single thermodynamic quantity is Gibbs free energy (G). The symbol for Gibbs free energy is ΔG (delta G). The sign of ΔG determines whether a reaction is spontaneous (negative ΔG) or non-spontaneous (positive ΔG).
Free Energy
Thermodynamics
Candle burning is a spontaneous reaction. It is an exothermic reaction that occurs naturally and releases heat and light energy as the wax is being oxidized in the presence of oxygen from the air.
A reaction is spontaneous if the Gibbs free energy change (ΔG) is negative. This means that the reaction can proceed without external energy input. In contrast, a reaction is nonspontaneous if ΔG is positive, meaning external energy is needed for the reaction to occur.
Free energy is the energy that is available to do work in a system. It is calculated as the difference between the enthalpy and the product of the temperature and entropy of a reaction. In a chemical reaction, the free energy change (ΔG) determines whether the reaction is spontaneous (ΔG < 0) or non-spontaneous (ΔG > 0).
If G < 0, the reaction is spontaneous.
This is a very fast reaction.
The symbol for free-energy change is ΔG (delta G). It represents the change in Gibbs free energy during a chemical reaction, which determines whether the reaction is spontaneous or non-spontaneous.
The spontaneity of a reaction is determined by the sign of the Gibbs free energy (ΔG). If both enthalpy (H) and entropy (S) are positive, the reaction can be spontaneous at high temperatures where the TΔS term outweighs the positive ΔH term, resulting in a negative ΔG. This means the reaction will be spontaneous at elevated temperatures.
Gibbs free energy represents the maximum reversible work that can be extracted from a system at constant temperature and pressure. It combines the system's enthalpy and entropy to predict whether a reaction is spontaneous. The change in Gibbs free energy (∆G) determines whether a reaction will proceed spontaneously or not.
Candle burning is a spontaneous reaction. It is an exothermic reaction that occurs naturally and releases heat and light energy as the wax is being oxidized in the presence of oxygen from the air.
A spontaneous reaction.
Thermodynamics
The reaction is spontaneous.
Thermodynamics
Whether a reaction took place is determined by the change in chemical composition, the formation of new substances, the release of energy or heat, and the color change or visible evidence of a chemical change. These factors indicate that a chemical reaction has occurred.
A reaction is spontaneous if the Gibbs free energy change (ΔG) is negative. This means that the reaction can proceed without external energy input. In contrast, a reaction is nonspontaneous if ΔG is positive, meaning external energy is needed for the reaction to occur.
spontaneous redox reaction