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The standard hydrogen electrode (abbreviated SHE), is a redox electrode which forms the basis of the thermodynamic scale of oxidation-reduction potentials.

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Q: What is an hydrogen electrode?
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What is mean by law hydrogen electrode?

The standard hydrogen electrode (SHE) is a reference electrode that is used to determine electrode potentials for other half-cell reactions. It has an assigned potential of 0 V at all temperatures. The SHE consists of a platinum electrode immersed in a solution of 1 M HCl and is in equilibrium with hydrogen gas at a pressure of 1 atm.


Which element is the reference element is chemistry?

Carbon is the reference element for the definition of the mole. In electrochemistry, the reference element/electrode is the Hydrogen electrode and all electrode potentials are against the hydrogen standard.


Why is standard hydrogen electrode called reversible electrode?

Depending on the other cell used, it can turn H+ ions into hydrogen gas, or it can turn hydrogen gas into H+ ions. Thus it is reversible.


How are standard electrode potentials determined for the half-cells listed in the Standard Reduction Potentials table?

Standard electrode potentials are determined through experiments where the half-cell reaction is coupled with a standard hydrogen electrode. By measuring the voltage generated, the standard electrode potential for the half-cell reaction can be calculated. The values in the Standard Reduction Potentials table are based on these experimental measurements.


Why is platinum coated with platinum black used in the standard hydrogen electrode?

Platinum black is a highly porous form of platinum that provides a large surface area for the reaction between hydrogen and protons. This allows for efficient hydrogen evolution or oxidation reactions at the electrode. The platinum coating ensures stability and resistance to corrosion during the electrode's use in electrolysis or other electrochemical experiments.

Related questions

What is standard hydrogen electrode?

The standard hydrogen electrode (SHE) is a reference electrode used in electrochemistry to measure electrode potential. It consists of a platinum electrode in contact with a solution of hydrogen ions at unit activity and surrounded by hydrogen gas at a pressure of 1 bar. The SHE has an assigned potential of 0 V at all temperatures.


What is mean by law hydrogen electrode?

The standard hydrogen electrode (SHE) is a reference electrode that is used to determine electrode potentials for other half-cell reactions. It has an assigned potential of 0 V at all temperatures. The SHE consists of a platinum electrode immersed in a solution of 1 M HCl and is in equilibrium with hydrogen gas at a pressure of 1 atm.


What is difference between standard hydrogen electrode and normal hydrogen electrode?

There is no difference between a standard hydrogen electrode (SHE) and a normal hydrogen electrode (NHE). Both terms refer to the same reference electrode commonly used in electrochemistry to establish a standard hydrogen half-cell potential of 0 V at all temperatures.


What is the use of mercury in standard hydrogen electrode?

Mercury is used in the standard hydrogen electrode as a platform to host the hydrogen gas phase. It allows for the measurement of the standard hydrogen electrode potential by providing a stable interface for the hydrogen gas to interact with the surrounding electrolyte solution.


Which element is the reference element is chemistry?

Carbon is the reference element for the definition of the mole. In electrochemistry, the reference element/electrode is the Hydrogen electrode and all electrode potentials are against the hydrogen standard.


Why is standard hydrogen electrode called reversible electrode?

Depending on the other cell used, it can turn H+ ions into hydrogen gas, or it can turn hydrogen gas into H+ ions. Thus it is reversible.


How do you separate the hydrogen from the oxygen in water?

You pass an electrical current through the water. The positive electrode will release oxygen while the negative electrode will release hydrogen.


Which electrode is used for welding of MS to SS?

We were told 309 was the electrode of choice.


Why hydrogen is used as a standard electrode?

Hydrogen is used as a standard electrode because it has a well-defined standard electrode potential and is easily reversible in its oxidation and reduction reactions. This makes it a reliable reference point for measuring the electrode potentials of other half-reactions in electrochemical cells.


Why is hydrogen produced at the negative electrode and not sodium?

Hydrogen is produced at the negative electrode during electrolysis because it is less reactive than sodium. Sodium ions are more likely to undergo reactions at the positive electrode because they are more reactive and readily lose electrons to form sodium metal. Hydrogen ions are less reactive and instead gain electrons at the negative electrode to form hydrogen gas.


What is the full form of NHE?

Normal Hydrogen Electrode


How should the values found using the zinc electrode as a standard compare with those based on the standard hydrogen electrode?

When using the zinc electrode as a standard, the values obtained will be relative to the standard hydrogen electrode (SHE). The potential difference between the two electrodes at a given condition can be used to calculate the standard electrode potential of the zinc electrode. This potential difference is due to the different standard hydrogen electrode potential (0 V) and standard zinc electrode potential (+0.76 V).