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Superscripts tend to be reserved for exponents, charge symbols and very little else. Subscripts commonly show what type of data is on display. For example if you have variable "t" in your equation (=time) then subscript "0" would mean when t=0...in other words, at the start of the experiment. Rate constant (K) is also prone to having subscripts attached, again they tell you about what this K relates to. Seeing "obs" as subscript tells you this is an observed rate constant, one that has been gained via experimental procedure rather than theoretical calculation.

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Q: What does subscript indicate in?
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