The missing polysaccharide is probably cellulose. Cellulose is the major constituent of plant cell walls.
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Starch is a storage polysaccharide. it is found in plants in the form of amylose and in the form of amylopectin.
starch
Plants store carbohydrates as starch for later use. Starch is a polysaccharide made up of glucose molecules and serves as a long-term energy storage molecule for plants.
Algae and plants store their food in the form of starch. Starch is a polysaccharide that serves as an energy reserve within their cells. During photosynthesis, algae and plants convert sunlight into chemical energy, which is then stored as starch for later use.
Starch belongs to the carbohydrate macromolecule family. It is a polysaccharide composed of glucose units and serves as a storage form of energy in plants.