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If you're asking me to explain how Thiosulfate-Iodine titration works, I'll explain.
Usually, this titration is used to calculate the amount of Iodide ions produced in a previous reaction, in order find the concentration of the substance reacted in that reaction.
For example, in an attempt to find the percentage of Copper in a coin, the coin is first dissolved in concentrated Nitric acid, where Cu2+ ions are formed. Next, this solution is treated with excess Potassium Iodide solution. The reaction is:
2Cu2+ + 4I- ----> 2CuI + I2
The amount of Iodine liberated is then titrated with a known concentration of Sodium Thiosulfate solution. The reaction is:
2S2O32- + I2 ----> S4O62- + 2I-.
Starch is used as indicator for this titration. The color at the end-point is bluish-black.
From the volume of Thiosulfate required, the amount of Iodide ions can be calculated(using the second equation). From this, the amount of Copper can be calculated from the first equation.
I hope this answers your question.
Redox titration iodometry is a technique that measures the concentration of oxidizing agents by using iodine as a redox indicator. In this method, iodide ions are oxidized to iodine by the analyte, and the iodine formed then reacts with a reducing agent to produce iodide ions again. The amount of iodine produced is used to determine the concentration of the oxidizing agent in the sample.
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What is the reason of heating solution during redox titration?
This is far to be a rule for this titration.
What are different types of titration?
There are several types of titration techniques, including acid-base titration (determining the concentration of an acid or base), redox titration (determining the concentration of oxidizing or reducing agents), complexometric titration (determining the metal ion concentration using a complexing agent), and precipitation titration (determining the concentration of a dissolved substance by precipitating it).
What is the chemistry behind the redox titration?
Redox titration involves a reaction between an oxidizing agent and a reducing agent. During the titration, electrons are transferred from the reducing agent to the oxidizing agent, resulting in a change in oxidation states. The equivalence point is reached when the moles of the oxidizing agent are stoichiometrically equivalent to the moles of the reducing agent.
Why potassium thiocyanate is added in redox iodometric titration of copper sulphate?
Potassium thiocyanate is added to the redox iodometric titration of copper sulfate to react with the excess iodine produced during the reaction. This reaction forms a stable product, potassium iodide, which helps reach the correct endpoint of the titration by preventing the iodine from reacting with other substances. It also helps improve the accuracy and precision of the titration results.
How is oxalic acid vs NaOH titration different from oxalic acid vs potassium permegnate titration?
In the titration of oxalic acid with NaOH, the acid-base reaction involves the neutralization of the acid by the base. However, in the titration of oxalic acid with potassium permanganate, the permanganate ion oxidizes the oxalic acid to carbon dioxide. This difference in reaction mechanisms leads to different equivalence points and color changes in the two titrations.
What is iodometry and iodimetry titration?
Iodometry is a quantitative analysis technique based on the measurement of the amount of iodine liberated in a chemical reaction, while iodimetry is a titration method that involves the use of iodine as a titrant to determine the concentration of an analyte in a sample. Iodometry is typically used to analyze reducing agents, while iodimetry is often employed in the analysis of oxidizing agents.
What is redox titration?
Redox titration is a type of titration that involves a redox reaction between the analyte and titrant. In this titration, the endpoint is determined by monitoring the change in oxidation state of the analyte. It is commonly used to determine the concentration of oxidizing or reducing agents in a sample.
Is iodometric titration and redox titration is same?
Iodometric titration is a type of redox titration where iodine is used as the titrant. Redox titration is a broader category that encompasses any titration based on a redox reaction, not necessarily involving iodine. So while iodometric titration is a type of redox titration, not all redox titrations involve iodine.
What is the theory of the redox titration?
Redox titration is a type of titration based on a redox reaction between the analyte and titrant. The theory behind redox titration is that the number of electrons transferred in the reaction is used to determine the amount of substance being analyzed. This is typically done by monitoring the change in concentration of a redox indicator or analyzing the endpoint using a potentiometric method.
What is the reason of heating solution during redox titration?
This is far to be a rule for this titration.
Difference between acid base titration and redox titration?
In acid-base titration, the reaction involves the transfer of protons between the acid and base, with the endpoint usually determined by a pH indicator. Redox titration, on the other hand, involves the transfer of electrons between the oxidizing and reducing agents, with the endpoint typically determined by a change in color or potential. Acid-base titrations are used to determine the concentration of acids or bases, while redox titrations are to determine the concentration of oxidizing or reducing agents.
How many tipes of titration?
There are several types of titration based on the nature of the reaction being examined, including acid-base titration, redox titration, complexometric titration, and precipitation titration. Each type of titration is used to determine the concentration of a specific analyte in a sample.
Why thiosulphate titration is called as redox titration?
Thiosulfate titration is called a redox titration because it involves a redox reaction between the thiosulfate (reducing agent) and the analyte (oxidizing agent). During the titration, the analyte oxidizes the thiosulfate while being reduced itself, resulting in a color change indicator that signals the equivalence point. This redox reaction is at the core of the titration process.
Why is no indicator needed in redox titration experiment?
No indicator is needed in redox titration because the endpoint of the titration is determined by a change in the appearance of the titrand. This change can be detected visually, such as a color change, indicating the completion of the reaction without the need for an indicator.
Why sulfuric acid is used in Redox titration instead of HNO3?
Sulfuric acid is commonly used in redox titrations because it is a strong acid and does not participate in the redox reactions. Nitric acid (HNO3) can act as an oxidizing agent itself, which can interfere with the redox titration process by introducing additional reactions.
What are the method of titration?
The methods of titration include acid-base titration, redox titration, and complexometric titration. Acid-base titration involves the reaction between an acid and a base to determine the concentration of one of the reactants. Redox titration involves oxidation-reduction reactions to determine the concentration of a substance. Complexometric titration involves the formation of a complex between a metal ion and a complexing agent to determine the concentration of the metal ion.
Where redox titration is used?
Redox titration is commonly used in analytical chemistry to determine the concentration of oxidizing or reducing agents in a sample. It is also used in industries such as food and pharmaceuticals to ensure product quality and compliance with regulations. Additionally, redox titration is employed in environmental monitoring to assess levels of pollutants in air, water, and soil.
