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The main reason for the difference in boiling points between methanal (formaldehyde) and ethanal (acetaldehyde) is the difference in molecular weight and size. Ethanal has a larger molecular size and weight compared to methanal, which leads to stronger intermolecular forces such as van der Waals forces, resulting in a higher boiling point for ethanal.

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Q: Main reason for the difference in boiling points of Methanal and Ethanal?
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