No, sadly the only woman is smurfett and she was made by the evil wizzard to luer The Smurfs into there doom. People would think Smurfs would need a mother but Smurfs may be more different from humans than they seem. I think the people who "made" Smurfs (the show) forgot to add Mama Smurf or they thought that Gargamell (spelled it way wrong, he's the evil wizard) destroyed her. So, sorry but no.
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Jonathan Winters
In a webserch there doesn't appear to be any such Smurf named Lily, so I'm going to say No since she doesn't seem to exist.
The first toy Smurfs were stuffed animals: Papa Smurf being one. They were first sold in the late 1970s.