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It is split like this: ap-ple.
ap·proachIf you need to see the syllable breakup for any words, just check out a dictionary or go to the related link.
there are three in the word syllable
Long syllable.
no word it isn't possible because if you take away one syllable from a five syllable word you get a four syllable word and there is no such thing as a "no syllable word"