The first sin was commited by Lucifer when he aspired to be greater than God. The first human sin was commited by Eve in the Garden of Eden, when she ate of the fruit that God had forbidden Adam or Eve to eat from.
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The first sin was when Eve partook the fruit of the tree of good and evil.
The word "sin" means to do wrong. The first wrong done by humans is found in Genesis chapter 3. The first murder was found in Genesis chapter 4.
The first deriviative of sin(x) is cos(x), which is also sin(x + pi/2). The general formula, then for the nth deriviative of sin(x) is sin(x + n pi/2).
Genesis 4:7.
The first person to SAY it is God to Adam. The first person to SIN is Eve.