When using the Hebrew (original) Tanach (the acronym of "Torah Nevi'im Ktuvim", and is the Jewish version, which is, again, the original), I'd say "Proverbs", unless you count "Shmuel A" and "Shmuel B" as one, and "Kings A" and "Kings B" as one, too (which is not correct, they are separate for a reason), and then it is "Song of the Songs"
I think Shmuel is know to you as Samuel, but I'm unsure.
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The 10th book in the old testament is the second book of Samuel.
In the book of Genesis, the first book of the Old Testament.
The book of Luke is found in the New Testament (not Old Testament) and is immediately followed by the book of John.
The fifth book of the old testament is the fifth book of Moses called Deuteronomy.
The book of Psalms is found in the Old Testament.