No it is not, it is a noun (naming word). The adjective for rain is rainy.
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Cautious IS an adjective. An adjective is an action!
The word 'rainy' is not a noun, it's an adjective, a word that describes a noun; for example a rainy day.The noun form is rain, a concrete noun; a word for a thing that can be seen and touched.
The word "it" is not an adjective (it is a pronoun). A word is an adjective if it modifies (defines, characterizes) a noun or pronoun. The big tent - big is an adjective He is tall - tall is an adjective This key - this (while arguably called a determiner) is a demonstrative adjective
probable is an adjective
Stable is an adjective.