The preposition between can be used to connect two or more subjects.
For example:
In between a man and his dog, is an everlasting relationship.
Let's keep this secret between you and me.
Our discussion meeting is between 2 o'clock and 3 o'clock.
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After is a preposition of time, usually. "My sister was born after me." Behind is a preposition (or adverb) of place. "Our house was behind the airport." (preposition); "The children walked behind." (adverb).
"Admit to"
A preposition will use an object (noun, pronoun, or an equivalent phrase). Example: Getting dirty is part of being a cowboy. (being a cowboy is a noun phrase, object of the preposition of) Where an adverb might also be used as a preposition, look for an object: a noun or pronoun or the equivalent which normally follows the preposition. If there is none, the word in that usage is an adverb. Example: We walked on. (adverb) We walked on the beach. (preposition)
The opposite directional preposition is from.
No, it is not a preposition. "Away" is an adverb or an adjective.