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Roman numerals are used to identify the oxidation state of transition metals with more than one possible oxidation state.
Roman numerals shown in a chemical formula, indicate the oxidation number of theprincipal metal ion. e.g. Fe(II)SO4 ; Ferric Sulphate Fe(III)SO4 ; Ferrous sulphate. KMnO4 = KMn(VII)O4 , Potassium permanganate . The manganese is in oxidation state (VII) ' '7'.
They are used to tell you which oxidation state the particular metal has when bonding to the non-metal. This is only done when the oxidation state can be more than one value.
No, Na2O does not have a Roman numeral. When we talk about sodium oxide (Na2O), we are dealing with sodium and oxygen. We know that sodium has a +1 oxidation state in nearly everything it reacts with. You can pretty much bet on it. As it is essentially always going to combine in this +1 oxidation state, there is no need to differentiate that oxidation state from another one, which is what Roman numerals do.Oxygen has (almost always) a -2 oxidation state, and that means it takes two +1's to balance with a -2. Sodium, with its +1 oxidation state, will combine in a two-to-one ratio with oxygen, with its -2 oxidation state, to make the oxide.
Typically use use the Roman numeral with a metal after a metal in an ionic compound to indicate which ion is indicated in the compound. The reason for this is that many metals can form more than one kind of ion. For example, copper can form Cu+ ions or Cu2+ ions, and iron can form Fe2+ ions and Fe3+ ions.