Most form bonds that last the lifetime of the pair. There are more males than females, so the odd male looks for females in other packs but do not form the long term bonds. The males gather around any female who is in heat. Her scent can be sensed miles away.
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Wolves find their mates by leaving their original pack, and searching across the searching for one. Eventually the two wolves will meet up and create a new pack, with them as the alphas.
Only the alpha or top wolf (male and female) are usaually permitted to mate. and they are a mating pair for as long as they hold the top spot.