No, in the phrase "this shirt," "this" is a demonstrative pronoun, not an adjective.
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The Hawaiian word for shirt is "kāmaʻa" or "kamale" depending on the style of shirt.
Yes. Same is an adjective because it is used to describe someone or something. Same can mean: 1) not different 2) exactly like someone or something else 3) not changed 4) exactly like an earlier version, event, etc. Example: Sarah wore the same shirt two days in a row.
Shirt in Portuguese is "camisa."
"His shirt is different from mine" is the correct phrase to use.