De-main or de-meen. The letter "s" is silent.
The word comes from the Old French word "demeine", like the more familiar word "domain". "Demesne" can be pronounced the same as the word "domain". It's not pronounced de-mez-nee or de-mess-nee, although that's usually how people who don't know otherwise will pronounce it.
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You pronounce it as dih-muh-NOO-shun.
"La-hoat" is how you would pronounce "Lahote."