No. You cannot buy duty free when travelling within the EU. It is the same whether you travel by train, car, airplane, ferry, on foot etc., no duty free.
Eurostar is the brand name of the company running high speed trains London-Paris and London-Lille-Brussels through the Channel Tunnel.
Eurostar uses the stations: St. Pancras (London), Gare du Nord (Paris), Bruxelles Midi (Brussels) and Lille Europe.
Currently these are the only passenger trains operating through the tunnel.
The Eurostar takes 2 hours 15 minutes between London and Paris. There is approximately one train per hour in each direction.
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