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Enayatolah Ghomashchi has written: 'Vibrational spectra of bridged metal complexes'
Peter Gardner has written: 'Vibrational spectroscopic studies of adsorbed species on metal surfaces'
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The vibrational energy in a molecule can be described by the quantum mechanical harmonic oscillator model. In this model, the vibrational energy levels are quantized and can be calculated using the equation E = (n + 1/2)hν, where E is the energy of the vibrational level, n is the vibrational quantum number, h is the Planck constant, and ν is the vibrational frequency of the oscillator.
Particles within are limited to vibrational motion, unlike the particles which make up liquids which can have vibrational & translational motion, and gaseous particles which have vibrational, translational and rotational motion.
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The vibrational energy levels of a diatomic molecule can be calculated using the formula E = (v + 1/2) * h * nu, where v represents the vibrational quantum number, h is Planck's constant, and nu is the vibrational frequency of the molecule. The first two vibrational energy levels would correspond to v=0 and v=1, with the energy difference between them being h * nu/2.
Some vibrational modes of benzene are IR inactive because they cause no change in the molecule's dipole moment. These modes involve symmetric stretching or bending vibrations where the charge distribution remains the same before and after the vibration. As a result, they do not produce an oscillating electric field that can interact with the incident IR radiation.
Laurence A. Nafie has written: 'Vibrational optical activity' -- subject(s): Vibrational spectra
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