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the answer is great britain

Although Britain or more accurately the United Kingdom was the first "Nation State", the first "Nation" where more than 50% of the population worked in industry was Wales which is part of the nation state of the United Kingdom but also a nation in the broader dictionary definition of the word nation.

na·tion   /ˈneɪʃən/ Show Spelled[ney-shuhn] Show IPA

-noun1.a large body of people, associated with a particular territory, that is sufficiently conscious of its unity to seek or to possess a government peculiarly its own: The president spoke to the nation about the new tax.

2.the territory or country itself: the nations of Central America.

3.a member tribe of an American Indian confederation.

4.an aggregation of persons of the same ethnic family, often speaking the same language or cognate languages

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Q: What is the world's first industrialized nation?
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