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Capsaicin is the active chemical in red peppers, used as "pepper spray" and heating rub. It is a nerve irritant and could cause damage to the blood vessel walls and any muscles it passed through. The effect on the heart and lungs would depend on the amount (concentration) but it would definitely be unpleasant for the injectee.

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Q: What would happen if you injected capsaicin into your vein?
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