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Condensation, just like your iced tea glass sweats because it is cold on the inside and the weather is hot on the outside.

Humidity supplies the moisture for the reaction.

Answer 2: Air from the kitchen, or wherever the unit is located, gets trapped inside the refrigerator. The cooler air inside condenses the moisture within the hotter outside air; the resulting moisture attaches itself to the interior walls of the refrigerator. This happens more often during humid days because there are more water particles within the air.

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