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Actually, Sokka could learn how to bend but never did. Michael Dante DiMartino (Creator of avatar) said Sokka had water bending potential but never realized it. But Sokka is okay with that because, apparently, he doesn't like many spiritual things.

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Q: Why does Katara have bending powers and Sokka does not?
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Who are the people in the Last Airbender and what are there powers?

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