Yes Defiantly I am 100 Percent Sure That You Can Use Canola Oil in A Cake In Fact I have A Canola Oil And Honey Cake That I bake Almost Every Month For My Friends So Yes I Am 120 Percent Sure You Can
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Canola oil is a "neutral" oil, meaning that it has no flavor of its own. It will not change the flavor of brownies unless it is used to replace butter. In that case, the brownies will not have a buttery flavor, a minor taste in such an intensely chocolate confection.
No, there is not a taste difference when using canola oil instead of vegetable oil.