You can most definitely use buttermilk for scalloped potatoes. It will give them a nice flavor. I suggest adding some fresh Rosemary to complement the twang of the buttermilk.
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Yes, buttermilk can be used when baking corn muffins if additional baking soda is added to counteract the acidity of the buttermilk.
Yes, they have many recipes online too. You can look up "Buttermilk Garlic Potatoes" and it will give you some results.