The name for the use of conventional keys harmony is 'tonality'.
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There is no difference between unconventional and non-conventional. You can use both either of these words to reference something that is not considered the norm.
Ovenproof refers to dishes that you can use in a conventional home oven.
Harmony means "in sync." So the word harmony does not necessarily mean a musical term. "Jesse's experiment and Kiley's written paper of the experiment were in perfect harmony with each other." "The cat and the dog live in harmony in the Jones household." "A piece of music does not have to have perfect harmony to be a powerful piece."
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A key enthusiast is one way to identify them. There is no actual term to refer to someone who collects keys out of enjoyment, but if they keep the keys out of fear that they may find a use for them after throwing them away, they are potentially a compulsive hoarder.