For the same power - Watts - you need to run twice as many amps at 220V than at 440V.
For the same load, it'll pull half the amps at 220V than it did on 440V
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It will not work at all.
My first thought is this is probably a corner grounded delta system, but I'm confused by your voltages. If this was a 460v (L-L voltage) ungrounded or corner grounded system, the phase to ground voltage is meaningless, but the phase to phas voltage will be 460v all around the delta. If you have a 460v system and you're only seeing 230v, there's something wrong.
First of all, a 150 HP 460V 3-phase motor only draws around 170A, so two of them would only draw 340A, not 800. 340A at 460V equals almost 300,000 watts (or 300kw), and the generator would need to be sized a little bigger than this to start such big motors.
Primary : 4 Secondary : 3/0 <<>> To answer this question correctly a voltage must be stated.
That's an 11% overvoltage (460/415), so this may be reaching the design limits of the transformer. If the system is actually run hot (say 105% of 460, or 480v), then I'd say no, unless specifically stated in test reports or design criteria. You should ask the manufacturer to be sure.