You can add citric acid and sugar to stop hydration. But then the concrete is unusable and you need to throw it away.
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you need to have a ''keyway''---that is a groove in the base concrete,can be cut in if concrete has set,if not set,oil a 2x4lightly(lightly) & imbed it into the base concrete flush.
yes they need to be set in concrete. depending on your fence, one bag of concrete per post should be enough.
The length of time that concrete takes to set, will depend on the temperature. It would take approximately 4 hours for concrete to set at a temperature of 80 degrees.
Regular sugar will cause the concrete to never set.
you can't once set.