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For hydrogen atoms to have the ability to create hydrogen bonds they must be bonded to an electronegative atom such as fluorine or oxygen. (This creates a partial positive charge on the hydrogen.) Since hydrocarbons are composed of only hydrogen and carbon there is no polarity in the bonds (electronegativity difference of 0.4).

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βˆ™ 14y ago
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βˆ™ 6mo ago

Hydrogen in hydrocarbons does not participate in hydrogen bonding because it does not have the necessary partial negative charge of an electronegative atom like oxygen or nitrogen to form hydrogen bonds. In hydrocarbons, hydrogen is bonded to carbon, which is less electronegative and does not result in a significant partial negative charge on hydrogen.

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Q: Why doesn't hydrogen in hydrocarbons make hydrogen bonds?
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