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Step 1: Na1+ + SO42- = Na2SO4 (you nees to balance out the charges of sodium and sulfate individually. Then you combine them and you get sodium sulfate.) Step 2: 2Na1+ + SO42-= Na2SO4 (Now the whole equation is balanced :) you have 2Na on the left to balance the 2Na on the right and SO4 is equal on both left and right side with a 1:1 molar ratio.

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