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A compound is where the elemental components are chemically bonded at the molecular level and can only be separated with great effort (not evaporation). The liquid could have been a mixture (hard water for example; water with minerals, fluoride, calcium, salt whatever) and the dissolved minerals left behind when the liquid evaporated. However the liquid itself could be a compound (such as pure water) but the fact it left behind 'impurities' when it evaporated means it became a mixture or colloid when the impurities mixed into the liquid. So if the container was completely clean when the liquid was put in and there was no possibility of impurities being introduced from the air or other sources, it was a mixture before it evaporated.

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