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Chocolate is primarily fat (due to the cocoa butter and added vegetable oils in cheap chocolate), however the sugar content determines how much of the chocolate is carbohydrate. Realistically, chocolate will always have a higher fat concentration than carbohydrate concentration, since the less fat it contains, the less it will "melt-in-your-mouth". I.e the more sugar you add, the crunchier it becomes, by which stage it's not really chocolate anymore.
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carbohydrate
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