It is backwards 5 liters have 21.13 cups.
1 liter = 4.22 cups
1 cup = 0.23 liter
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250 mls per cup, so 4 cups per liter... so 5.5 liters is 22 standard cups (not coffee cups!)
NONE - kilometers is a measure of length equal to 1,000 meters. - Nothing to do with weight or volume.