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While keeping it sealed protects from evaporation and contamination, It doesn't protect it from things like gravity or chemical changes. Over time the ink will thicken, harden, or coagulate naturally, even without exposure to the air. The expiration date on it isn't there just as a marketing ploy after all. It's a prediction of when these things are expected to occur.

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Q: Why won't your sealed ink-jet cartridge that expired in the 1990s' print?
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