If you mean the key between the zero and the equal, it is hyphen "-" or with the shift key, underline "_".
Hyphen is used in some compound words such as "old-fashioned."
Two hyphens together mean the same as a dash (and some computer programs convert them to a dash). This would be used between phrases, similarly to a semicolon, such as: "Buy now--the sale will end soon!"
The underline can be used to show a blank, such as when the word will be filled in later, such as: "We lived on Green Street from ___________ till November of 2001." On old-fashioned typewriters, to underline a word for emphasis you would type the word, backspace, and add the underline. Now with computers we use control-U to emphasize, like this.
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