You do not format a column, you format a cell. If course, you can format all cells in the column to accomplish what you are asking. To format an entire column, click on the letter at the top of the column, then select cell format and make your selections.
Since there are hundreds of ways to format a cell, I will not list them all here. Some of the ways to format cells are: by color (cell background and font), by font attribute (bold, face, size, etc.), cell border (multiple assortment of lines and colors), by number attribute (time, percent, currency, etc.), and many more.
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