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Isomerisation causes straight chain alkanes to become branched alkanes which prevents the chains from moving to close proximities of each other. This reduces the van der Waal's intermolecular forces between chains so less energy is needed to overcome the forces and thus a lower boiling point.

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6mo ago

Isomerisation rearranges the atoms in a molecule to form isomers with different structures. In the case of straight chain alkanes, isomerisation can lead to branching in the molecule, which decreases the surface area available for intermolecular forces such as Van der Waals interactions. This results in weaker forces between the isomers, leading to lower boiling temperatures compared to straight-chain alkanes.

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A straight-chain alkane will have a boiling point higher than a branched-chain alkane due to the greater surface area in contact, thus the greater van der Waals forces, between adjacent molecules.

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Q: Why does isomerisation turn straight chain alkanes into alkanes with lower boiling temperature?
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Why alcohol have higher boiling point than alkanes?

Alcohols have higher boiling points than alkanes because alcohols can engage in hydrogen bonding between the hydroxyl (-OH) groups, which increases the intermolecular forces between molecules. This stronger intermolecular attraction requires more energy to break the bonds and thus results in a higher boiling point for alcohols compared to alkanes, which only have weaker London dispersion forces.


What is it called the temperature at which a liquid boils?

The temperature at which a liquid boils is called its boiling point.


Which has higher boiling point aldehyde or ketone?

In general, aldehydes have lower boiling points than ketones due to the presence of a hydrogen bond in aldehydes that is absent in ketones. This hydrogen bond in aldehydes results in weaker intermolecular forces compared to ketones, leading to lower boiling points.


How can you use boiling points and melting points to determine a solid liquid or gas that an element would be in at a certain temperature?

By comparing the temperature to the melting point and boiling point of the element, you can determine what state it would be in. If the temperature is below the melting point, the element would be a solid. If the temperature is between the melting and boiling points, the element would be a liquid. If the temperature is above the boiling point, the element would be a gas.


How can the temperature in the autoclave go above boiling temperature of 212 F?

The temperature in an autoclave can go above the boiling temperature of 212°F by increasing the pressure inside the autoclave. As pressure increases, the boiling point of water also increases. This allows the autoclave to achieve temperatures higher than the standard boiling point of water.

Related questions

How do oil companies use cracking isomerisation and reforming to process fractions from crude oil?

Oil companies use cracking to break down larger hydrocarbon molecules into smaller ones, producing gasoline and other light products. Isomerisation is used to rearrange the structure of hydrocarbon molecules to create isomers with different chemical properties. Reforming involves changing the molecular structure of hydrocarbons to create higher-value products like gasoline and diesel.


Which of the alkanes are liquids at room temperature?

Alkanes with 5 to 17 carbon atoms are typically liquids at room temperature. Examples include pentane, hexane, heptane, octane, nonane, decane, undecane, dodecane, tridecane, tetradecane, pentadecane, hexadecane, heptadecane, octadecane.


How can alkanes be described?

Alkanes are hydrocarbons with only single bonds between carbon atoms, making them saturated hydrocarbons. They are colorless, odorless, and nonpolar molecules that are relatively unreactive under normal conditions. The physical properties of alkanes, such as boiling point and solubility, increase with increasing molecular weight.


What is the volatility of Alkanes?

Alkanes are considered nonpolar and have low volatility due to the strong London dispersion forces between molecules. Their boiling points generally increase with increasing carbon chain length.


How does a substance's boiling point determine its state at room temperature?

A substance's boiling point indicates the temperature at which it transitions from a liquid to a gas. If the substance's boiling point is below room temperature, it will be a gas at room temperature. If the boiling point is above room temperature, it will be a liquid at room temperature.


Why alcohol have higher boiling point than alkanes?

Alcohols have higher boiling points than alkanes because alcohols can engage in hydrogen bonding between the hydroxyl (-OH) groups, which increases the intermolecular forces between molecules. This stronger intermolecular attraction requires more energy to break the bonds and thus results in a higher boiling point for alcohols compared to alkanes, which only have weaker London dispersion forces.


What is it called the temperature at which a liquid boils?

The temperature at which a liquid boils is called its boiling point.


How long to poach pork?

If the water is boiling before you add the egg and the egg is at room temperature, (i.e. not straight out of the fridge) then around 2.5 minutes.3 minutes in softly boiling water.


Can boiling temperature of an element change?

The boiling temperature of an element can change by changing the pressure.


What is the saturation temperature of vapour or the boiling temperature of a liquid?

The saturation temperature of a vapor is the temperature at which it condenses to a liquid at a given pressure. It is also known as the boiling temperature of a liquid, as it is the temperature at which the vapor pressure of the liquid equals the surrounding pressure, resulting in boiling.


At what temperature does a liquid become a gas?

At it boiling point: boiling temperature AND pressure:Water boiling at 100oC at 100 kPa (1 atm.)


How alkanes are produced?

Alkanes are primarily produced through petroleum refining, where crude oil is distilled and processed to separate out hydrocarbon fractions based on their boiling points. Another method is through the catalytic hydrogenation of alkenes or alkynes. Additionally, alkanes can be synthesized in the laboratory by reacting alkyl halides with metallic reducing agents.